Serpentine is certainly the way to go. I might do some serpentine dream shopping for my 318, before I go through the effort of replacing my useless AC compressor with second alternator
One potential solution of the squealing belt is to reduce the current the depleted battery can draw on start up through your 2 AWG (?) cable.
Run in a parallel + circuit from alternator to solenoid to fuse to house battery. Have this second solenoid also manually triggered, by a rocker switch next to the existing one you already employ.
10AWG will likely limit the 50% charged battery to accepting 35 amps or less when your voltage regulator inside your internally regulated alternator is still seeking mid 14.5v while it is still cold.
With just one healthy flooded group 31? marine battery it would only be able to accept 30 amps for about 25 minutes with VR seeking 14.5v whereas with 2awg it is likely to accept double that for 8 to 10 minutes before reaching 14.4v at which point amps taper.
Once the belt and pulleys are warm and dry, the V belt is less likely to slip, and you can then trigger the existing circuit's solenoid, and these dual parallel circuits will then allow more voltage to reach the battery and it can then recharge faster as amps taper from 60? downwards as it climbs in state of charge.
The question mark is I forget how much amperage you measured going into the battery just before it starts squealing , or just after it stops squealing.
Expect the 'during squealing' amps, to be lower than non squealing.
Huge amperages can really return a healthy well depleted lead acid battery quickly to ~75% state of charge, and while a flooded marine battery should likely not see this every single day on every recharge, one must factor in the damage to battery if it only gets 87% charged 5 days in a row via solar alone. Compare this to whetherf huge alternator amperages first thing in the morning, when it is most depleted, do then allow the solar to get it closer or preferably to 100% state of charge by afternoon. Meaning the alternator can do in 10 minutes what will take the solar 2 hours when the battery is well depleted.
The additional parallel circuit is a nice redundancy, as you will have a second solenoid should the primary one fail out in the stix.
Your internally regulated 1 wire alternator likely drops the max allowed voltage once it warms up.
Once it is warmed up and the max voltage drops, so does the amperage the battery can accept, and the slower it charges.
Mainesail explains it well here:
https://marinehowto.com/automotive-alter...batteries/
So you might only need a few minutes of engine running before you can flip both solenoid trigger switches, and let her rip.
The less healthy the battery, the less amperage and lesser times are required to bring the depleted battery to absorption voltage. So your existing belt squealing, when well depleted, could be a sign your battery is still pretty healthy, as you regularly charge it via solar.
But collect the actual data with your ammeter, as it will help you learn what you can expect from your system, and as you learn, you will then easily be able to notice when the battery is aging and its capacity and performance becomes limited, and wont be surprised having to battery shop during some crazy event, like the after effects of a protracted Pandemic MadMax world.